Co-synthesis of vertical graphene nanosheets and high-value gases using inductively coupled plasma enhanced chemical vapor deposition

摘要

One-step controllable synthesis of vertical graphene nanosheets (VGs) and high-value gases was achieved using inductively coupled plasma enhanced chemical vapor deposition (ICPECVD).The basic physical properties of the ICPECVD process were revealed via electrical diagnosis and optical emission spectroscopy. The coil current and voltage increased linearly with the augmenting of injected power, and CH, C_2, H_2 and H were detected at a wavelength from 300 to700 nm, implying the generation of abundant graphene-building species. The morphology and structure of solid carbon products, graphene nanosheets, were systemically characterized in terms of the variations of operating conditions, such as pressure, temperature, gas proportion, etc.The results indicated that an appropriate operating condition was indispensable for the growth process of graphene nanosheets. In the present work, the optimized result was achieved at the pressure, heating temperature, applied power and gas proportion of 600 mTorr, 800 °C, 500 W and 20:20:15, respectively, and the augmenting of both CH_4 and H_2 concentrations had a positive effect on the etching of amorphous carbon. Additionally, H_2 and C_2 hydrocarbons were detected as the main exhaust gases. The selectivity of H_2 and C_2 H_2, measured in exhaust gases,reached up to 52% and 8%, respectively, which implied a process of free radical reactions and electron collision dissociation. Based on a comprehensive investigation of spectral and electrical parameters and synthesized products, the reaction mechanism of collision, dissociation,diffusion, etc, in ICPECVD could be speculated, providing a probable guide for experimental and industrial applications.