N-（末端三丁基锡取代基）酰亚胺的光诱导电子转移成环反应

摘要

合成了两种新的分子内给受电子体系N-（3-三丁基锡丙基）马来酰亚胺（1a）和N-（2-三丁基锡亚甲基硫乙基）邻苯二甲酰亚胺（1b）,在甲醇、乙腈、乙腈-30%H2O进行了光反应,得到了三个新的环化物.%Two novel intramolecularly electronical donor - acceptor systeme ( 1 a) and N - ( 2 - tributylmethylenesulfenylethyl ) phthalimide ( 1 b ) methanol, in acetonirile, acetonirile - 30% H2O, provided three new N - (3 - tributylstanyl) ma - leimide , are synthesized, and irradiated in cyclic compounds.