A superhard α-Si3N4 film,deposited on metal substrate,was produced by laser chemicalvapor deposition adopting a kW-level high power CO2 laser.Most films are composedof fine Si3N4 partieles.They join the metal substrate in strong bond.The films havesuper hardness,excellent resistance to wear and corrosion,etc.Their thickness may becontrolled within 5-30 μm.
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