氢气易燃易爆,在工业生产中,快速、准确地对其进行检测是非常必要的.采用AAO模板法制备Pd-Pt合金纳米线,电化学沉积溶液的配制如下:60 mmol/L的PdCl2+40 mmol/L的H2PtCl6·6H2O+0.2 mol/L的H3BO3,pH值为5.9.实验参数选择设置为-0.4V(1s),0 V(3 s),沉积2 h,能谱(EDX)测得Pt质量分数为30%左右.%In chemical production, the in situ rapid accurate and quantitative monitoring of hydrogen has important significance for safety production because of its inflammable and explosive properties. In the study, we first prepared the Pd-Pt alloy nanowires with AAO as the template by potentiostatic pulse electrodeposition in the solutions of 0.2 mol/L H3 BO3 containing 60 mmol/L PdCl2 and 40 mmol/L H2PtC16 · 6H2 O with pH value of 5.9. For pulsed electrodeposition, rectangular potential pulses were used. During each pulse, a potential of -0.4 V versus SCE was applied for 1 s, followed by a potential of 0 V versus SCE being applied for 3 s, with the effective electrodeposition time of 2 h. The energy spectrum suggested content of Pt -was approximately 30％.
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