Synthesis, Spectral Characterization and Thermal Behavior of Newly Derived La(III), Co(III) and Mn(II) Complexes with Schiff Base Derived from Methionine and Salicylaldehyde

摘要

Many metal complexes of Schiff base derived from different amino acids are widely employed as biologically active materials, especially as antibacterial agents. Three new metal [Co(III), Mn(II) and La(III)] complexes with the Schiff base (L) derived from salicylaldehyde and amino acid (methionine) were synthesized and investigated by using various physico-chemical techniques such as elemental analysis, FTIR, UV-visible spectroscopy, magnetic measurement, thermo gravimetric analysis (TGA) and X-ray powder diffraction (XRD) method. From spectral studies, it has been concluded that the synthesized ligand acts as a tetra-dentate molecule, coordinates metal through azomethine nitrogen, sulfur, phenolic oxygen and carboxylate oxygen. UV-visible spectrophotometry showed the characteristic absorption bands corresponding to a square planar geometry for La(III) and Mn(II) metal complexes and tetrahedral geometry for Co(III) complex. The XRD data demonstrated that the manganese and cobalt complexes were crystalline but the lanthanum complex was amorphous in nature. The empirical formula of the synthesized complexes based on analytical data were [Co(C12H13SNO3)]·(NO3), [La(C12H13SNO3)](Cl)(H2O) and [Mn (C12H13SNO3)].