首页> 中文期刊> 《中国稀土学报:英文版》 >Hydrogen Absorption Thermodynamic Properties of Rare Earth Based Hydrogen Storage Alloy in Benzene

Hydrogen Absorption Thermodynamic Properties of Rare Earth Based Hydrogen Storage Alloy in Benzene

         

摘要

The hydriding/dehydriding thermodynamic properties of the slurry system formed by suspending La rich mischmetal nickel hydrogen storage alloy (MlNi 5) in Benzene (C 6H 6) were investigated. The pressure composition isotherms for both the alloy powder and the slurry suspended with MlNi 5 were measured at several temperatures(10, 20, 30, 40 ℃). The standard enthalpy of formation Δ H ° and standard entropy of formation Δ S ° for the alloy powder with and without benzene were determined respectively. The experimental results show that the values of Δ H ° and Δ S ° for the hydriding reaction of hydrogen storage alloy (MlNi 5) of the slurry system and the gas solid system are all very close.

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