具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究

摘要

A planar metal complex NiL,H2L = acenaphthenequinone bis(S-benzyldithiocarbazate),1,has been prepared via the template effect of nickel ion.Crystal structure of 1 was determined by X-ray diffraction analysis and shows the planar coordination configuration around the central nickel atom.Z-scan measurements show that 1 is a transition metal complex exhibiting high third-order nonlinear optical effect.