两个由2-(4′-氯-苯甲酰基)苯甲酸构筑的铜、锰配合物的合成及晶体结构

摘要

Two new complex [Cu(cbba)2(im)2] (1) and {[Mn(cbba)2(bipy)(H2O)2]· bipy}n (2) (Hcbba=2-(4′-chlorinebenzoyl)-benzoic acid,im=imidazole,bipy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions.CCDC:834794,1; 834795,2.%通过水热法合成了2个新的配合物[Cu(cbba)2(im)2](1)和{[Mn(cbba)2(bipy)(H2O)2]·bipy}n (2)(Hcbba=2-(4′-氯-苯甲酰基)苯甲酸,im=咪唑,bipy=4,4′-联吡啶).并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定.这2个配合物通过氢键或π-π相互作用形成了三维超分子网状结构.