MnCl2· 4H2O与吡嗪-2,3,5,6-四甲酸(H4pztc),1,10-邻菲罗啉(phen)通过水热反应合成了1个Mn的配位聚合物{[Mn2(phen)2(H2pztc)Mn2(phen)2(Hpztc)2(H2O)2]·4H2O}n(1),并对配合物进行了IR、元素分析、X-射线单晶结构解析及磁性分析等表征.配合物1属于三斜晶系,P-1空间群,a=0.95502(19) nm,b=1.3234(3) nm,c=1.5157(3) nm,α=68.95(3)°,β=77.33(3)°,γ=81.92(3)°,V=1.7403(6) nm3,Z=2.配合物中Mn(Ⅱ)离子为六配位和七配位,通过配体pztc与phen的连接形成一维链状结构.变温磁化率测试结果表明,在配合物1中,Mn(Ⅱ)离子之间存在反铁磁相互作用.%Coordination polymer {[Mn2(phen)2(H2pzte)Mn2(phen)2(Hpzte)2(H2O)2] · 4H2O}n (1) has been synthesized by the hydrothermal reaction of MnCl2· 4H2O, pyrazine-2,3,5,6-tetracarboxylic acid (H4pzte) and 1,10-phenanthroline (phen), which were further characterized by IR, elemental analysis, X-ray diffraction single-crystal structural analysis and magnetic susceptibility. It belongs to triclinic crystal system, P1- space group with a=0.955 02(19) nm, 6 = 1.323 4(3) nm, c = 1.515 7(3) nm, a=68.95(3)°, β=77.33(3)°, γ=81.92(3)°, V=1.740 3(6) nm3, Z=2. The manganese (Ⅱ) ions in the complex are 6-coordinated and 7-coordinated. The Mn (Ⅱ) ions of complex 1 are connected by pztc and phen, resulting in a 1D chain. Variable temperature magnetic susceptibility measurements reveal the existence of antiferromagnetic interactions in the complex 1. CCDC: 694108.
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