Separation process undertaken in packed columns often displays anisotropic turbulent mass diffusion. The anisotropic turbulent mass diffusion can be characterized rigorously by using the Reynolds mass flux(RMF) model.With the RMF model, the concentration and temperature as well as the velocity distributions can be simulated numerically. The modeled Reynolds mass flux equation is adopted to close the turbulent mass transfer equation,while the modeled Reynolds heat flux and Reynolds stress equations are used to close the turbulent heat and momentum transfer equations, so that the Boussinesq postulate and the isotropic assumption are abandoned. To validate the presented RMF model, simulation is carried out for CO2 absorption into aqueous Na OH solutions in a packed column(0.1 m id, packed with 12.7 mm Berl saddles up to a height of 6.55 m). The simulated results are compared with the experimental data and satisfactory agreement is found both in concentration and temperature distributions. The sequel Part II extends the model application to the simulation of an unsteady state adsorption process in a packed column.
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