A New Method for Decreasing Mass Limit of Detection and Increasing Number of Theoretical Plates in Capillary Electrophoresis with Amperometric Detection

摘要

A new method was developed to decrease the mass limit of detection (LOD) and increase the number of theoretical plates (N) in capillary electrophoresis with amperometric detection. When the single microcylinder electrode, the 10 靘 ID capillary with the etched detection end and the in-capillary alignment were used, the mass LOD for phenol was reduced 124 times and N was increased 36 times in comparison with the normal situation.