2D Naphthalenedisulfonate-cadmiun coordination polymer with2,4,5-tri(4-pyridyl)-imidazole as a co-ligand:Structure and catalytic property

摘要

A new 2D coordination polymer,[Cd(tpim)(1,5-nds)]_n(1),was constructed from 1,5-naphthalenedisulfonate(1,5-nds),2,4,5-tri(4-pyridyl)-imidazole(tpim) and Cd(CH_3COO)_2·2H_2O,which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity.In addition,the thermal and luminescent properties of 1 in the solid state were also investigated.