The article deals the structure of the CaO- Al_2O_3-TiO_2-SiO_2 system as a basis for obtaining advanced ceramics with a complex of high-operational characteristics.As a result of investigations the phase characteristics are represented and the graph of the relationship of the elementary tetrahedra has been plotted.The most technological system area for the production of heat resistant advanced ceramics has been determined.The batches for producing heat and chemical resistant dense advanced ceramics made of natural, technical and technogenic raw materials have been developed.
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