A rotating ring (Pt) disc (Pt) electrode was employed to investigate the oxidation process of sodium sulfide (Na 2S). It was reported that the oxidation intermediates and product of HS - were formed on the disc electrode and then reduced on the ring electrode. The results indicate that at a rotation rate of 20 Hz, when the disc electrode potential was -0.15 V (vs SHE) and higher, more extensive oxidation process took place via a series of electrochemical steps to produce sulfur (S). The products of oxidation intermediates (S 2- x , S 2- 2) and sulfur (S) reduced either on the ring electrode with a set potential of -0.8 V (vs SHE), or on disc electrode with negative going potential sweep at about -0.5～ 0.55 V (vs SHE). The experimental results of voltammogram of ring disc electrode at sodium sulfide solution demonstrated that the first step was the oxidation of HS - and produce S 2- x , and then the S 2- x adsorbed integrated itself and formed sulfur (S).
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