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《中国有色金属学报:英文版》
>A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ)--Surface complexation model at TiO_2/water interface
A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ)--Surface complexation model at TiO_2/water interface
The kinetics of photocatalysis can be usually described by Langmiur Hinshelwood adsorption expression. The adsorption can be greatly influenced by the surface properties of photocatalyst. Triple layer model (TLM) was chosen to describe the surface adsorption of TiO 2 based on electrical double layer (EDL) theory at the TiO 2/water interface. And through the potentiometric titration the parameters of TLM were determined by the extrapolation method and Fiteql3.1 software. The results show that surface complexation dominates the surface charge and the numerical calculation fits the experiment data satisfactorily.
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机译:An Innovative Workflow for Appropriate Selection of Subsurface-Surface Model Integration Scheme Based on Petroleum Production System Nature, User Needs,and Integrated Simulation Performance