Guangzhou Municipal and Guangdong Provincial Key Laboratory of Molecular Target&Clinical Pharmacology;
NMPA and State Key Laboratory of Respiratory Disease;
School of Pharmaceutical Sciences and the Fifth Affiliated Hospital;
Guangzhou Medical University;
Guangzhou 511436;
China;
Gem-difluoromethylene allenes; C-H functionalization; Regiocontrol; Rhodium(Ⅲ)catalysis; DFT calculations;