N,N'-二四唑胺过渡金属配合物M(BTA)(H2O)n对RDX和HMX热分解行为的影响

摘要

The effects on the thermal decomposition behavior of five transitions metal N,N' -bis-(1(2)H-tetrazol-5-yl-)amine complexes M(BTA) ( H2O)n(M = Mn,Co,n=4;M =Ni,n=3;M =Zn,n=3.5; M = Pb,n=2;BTA2-=N,N'-bis-(1(2)H-tetrazoI-5-yl-)amine ion) act on RDX and HMX were investigated with DSC technique. The experimental results were evaluated from characteristic parameters, such as maximum decomposition peak temperature, critical temperature of thermal explosion.%利用DSC技术研究了5种N,N’-二四唑胺过渡金属配合物MBTA(H2O)n(M=Mn、Co,n=4；M=Ni,n=3；M =Zn,n=3.5；M=Pb,n=2；BTA2-=N,N’-二四唑离子)对RDX和HMX热分解行为的影响,从分解峰温、热爆炸临界温度等特征参数评价了配合物对RDX和HMX热分解行为的影响效果.