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Low density materials through freeze-drying: Clay aerogels and beyond..

机译:通过冷冻干燥的低密度材料:粘土气凝胶及其他

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摘要

Clay aerogels and other ice templated materials belong to a family of materials with properties similar to those of conventionally foamed polymers including low density, high porosity and low thermal conductivity. The ice templating process represents an environmentally friendly method for producing light weight alternatives to typical polymer foams. The properties of these materials can be controlled using many variables such as component shape, size, and chemistry. Sub-micron scale fillers are able to be incorporated into the lamellar structure while larger particles are deposited on the surfaces. The molecular weight and chemistry of the reinforcing polymer also plays a significant role in the structure and properties seen in these materials. Controlling the directionality of ice crystallization, as well as nucleation, provides an additional level of manipulation with which the properties can be tailored. In addition to providing stand alone structural materials, ice templated materials can provide a foundation for developing novel clay/polymer nanocomposite materials. The nanocomposites created via ice templating exhibit properties comparable to those seen in organically modified clay/polymer composites without the need for organic modification of the clay.
机译:粘土气凝胶和其他以冰为模板的材料属于一类材料,其性质类似于常规发泡聚合物,包括低密度,高孔隙率和低导热率。冰模板工艺代表了一种环境友好的方法,用于生产轻质替代典型聚合物泡沫的材料。可以使用许多变量来控制这些材料的属性,例如组件的形状,大小和化学性质。亚微米级的填料能够被引入到层状结构中,同时较大的颗粒沉积在表面上。增强聚合物的分子量和化学性质在这些材料中看到的结构和性能中也起着重要作用。控制冰结晶的方向性以及成核作用,提供了附加的操纵水平,可以通过这些操纵来调整属性。除了提供独立的结构材料外,冰模板材料还可以为开发新型粘土/聚合物纳米复合材料提供基础。通过冰模板制备的纳米复合材料表现出的性能可与有机改性的粘土/聚合物复合材料相比,而无需对粘土进行有机改性。

著录项

  • 作者

    Gawryla, Matthew Daniel.;

  • 作者单位

    Case Western Reserve University.;

  • 授予单位 Case Western Reserve University.;
  • 学科 Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 2009
  • 页码 221 p.
  • 总页数 221
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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