首页> 外文学位 >Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation

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Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation

机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺

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作者
Shin, Hyunshun;
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作者单位

Drexel University;

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授予单位 Drexel University;
学科
学位 Ph.D.
年度 2001
页码 240 p.
总页数 240
原文格式 PDF
正文语种 eng
中图分类
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专利

1. Fukuyama-Mitsunobu alkylation in amine synthesis on solid phase revisited: N-alkylation with secondary alcohols and synthesis of curtatoxins [J] . Olsen CA, Witt M, Hansen SH, Tetrahedron . 2005,第25期

机译：再谈固相胺合成中的福山光延烷基化：仲醇的N-烷基化和姜黄毒素的合成
2. Fukuyama-Mitsunobu alkylation in amine synthesis on solid phase revisited: N-alkylation with secondary alcohols and synthesis of curtatoxins [J] . Olsen CA, Witt M, Hansen SH, Tetrahedron . 2005,第25期

机译：再谈固相胺合成中的福山光延烷基化：仲醇的N-烷基化和姜黄毒素的合成
3. Highly efficient and eco-friendly synthesis of tertiary amines by reductive alkylation of aldehydes with secondary amines over a Pt nanowires catalyst [J] . Wu Junjie, Lu Shuanglong, Ge Danhua, RSC Advances . 2015,第99期

机译：通过在PT纳米线催化剂上用仲胺的醛烷基化通过醛烷基化的高效和生态友好合成。
4. A Novel Reductive N-Alkylation in a Triruthenium Carbonyl Cluster-Catalyzed Reduction of Secondary Amides with Polymethylhydrosiloxane:A New Entry to the Facile Synthesis of Tertiary Amines [C] . Yukihiro Motoyama, Toshiki Ishida, Shiori Hanada Symposium on Organometallic Chemistry . 2006

机译：用聚甲基氢硅氧烷的三rruthenium羰基簇催化还原仲酰胺的新型还原N-烷基化：第三胺的体内合成的新进入
5. Mechanistic Studies of Electrocatalytic Processes: Upgrading of Lignin Monomers to Biofuels (Probing Substrate Synergy); Alkylation of Amines with Alcohols Via Borrowing Hydrogen Mechanisms; and Reduction of the Carboxylic Acid Functionality in Amino Acid [D] . ?Appiagyei, Benjamin 2020

机译：电催化工艺的机械研究：将木质素单体升级到生物燃料（探测底物协同）; 通过借用氢机制烷基化胺与醇的烷基化; 并降低氨基酸中的羧酸官能团
6. The Design of a Photoredox Catalyst that Enables the Direct Synthesis of Carbamate-Protected Primary Amines via Photoinduced Copper-Catalyzed N-Alkylation Reactions of Unactivated Secondary Halides [O] . Jun Myun Ahn, Jonas C. Peters, Gregory C. Fu -1

机译：能够通过未活化的二级卤化物的光诱导的铜催化的N烷基化反应直接合成氨基甲酸酯保护的伯胺的光氧化还原催化剂的设计
7. The Ruthenium-Catalyzed Reduction and Reductive N-Alkylation of Secondary Amides with Hydrosilanes: Practical Synthesis of Secondary and Tertiary Amines by Judicious Choice of Hydrosilanes [O] . -1

机译：氢钌催化的氢硅酸甘露硅氧酰胺的还原和还原N-烷基化：通过明智选择水硅烷的二级和叔胺的实际合成
8. Alkylation of Amines: A New Method for the Synthesis of Quaternary Ammonium Compounds from Primary and Secondary Amines [R] . Sommer, H. Z., Jackson, L. L. 1969

机译：胺的烷基化：从伯胺和仲胺合成季铵化合物的新方法

Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation

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