首页> 外文学位 >PART I: BASE-HYDROLYSIS OF HALOLACTONES. THE MECHANISM OF KETONE FORMATION IN THE BICYCLO(2.2.1)HEPTYL SYSTEM. PART II. ACID-CATALYZED LACTONIZATION. ELECTROPHILIC REACTIVITY OF BICYCLO(2.2.2)OCT-5-ENE-2-CARBOXYLIC ACIDS.

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PART I: BASE-HYDROLYSIS OF HALOLACTONES. THE MECHANISM OF KETONE FORMATION IN THE BICYCLO(2.2.1)HEPTYL SYSTEM. PART II. ACID-CATALYZED LACTONIZATION. ELECTROPHILIC REACTIVITY OF BICYCLO(2.2.2)OCT-5-ENE-2-CARBOXYLIC ACIDS.

机译：第一部分：半乳糖内酯的碱水解。双环（2.2.1）庚基体系中酮形成的机理。第二部分酸催化的离子化。双环（2.2.2）OCT-5-ENE-2-羧酸的亲电反应性

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作者
ADAMS, TIMOTHY BRIAN.;
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作者单位

The Catholic University of America.;

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授予单位 The Catholic University of America.;
学科 Organic chemistry.
学位 Ph.D.
年度 1972
页码 152 p.
总页数 152
原文格式 PDF
正文语种 eng
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专利

1. The unexpected formation of bicyclo[2.2.1]heptane derivatives by Lewis acid-catalyzed transannular double cyclization [J] . Majo VJ., Toyota M., Ihara M., Journal of the Chemical Society, Perkin Transactions 1 . 2000,第20期

机译：Lewis酸催化的跨环双环化意外形成双环[2.2.1]庚烷衍生物
2. First example of stepwise, zwitterionic mechanism for bicyclo[2.2.1]hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations [J] . Jasinski Radomir Monatshefte fur Chemie . 2016,第7期

机译：1-丁基-3-甲基咪唑鎓阳离子催化双环[2.2.1]庚-5-烯（降冰片烯）形成过程的两性离子机理的第一个实例
3. I. Formylation of kinetically-generated ketone enolates. II. Synthesis of bridgehead functionalized bicyclo[2.2.2]octanes. III. Synthesis of [n.2.2.2]paddlanes. [D] . Zayia, Gregory. 1999

机译：I.动力学产生的酮烯酸酯的甲酰化。二。桥头官能化的双环[2.2.2]辛烷的合成。三， [n.2.2.2] paddlanes的合成。
4. First example of stepwise zwitterionic mechanism for bicyclo2.2.1hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations [O] . Radomir Jasiński -1

机译：1-丁基-3-甲基咪唑鎓阳离子催化双环2.2.1庚-5-烯（降冰片烯）形成过程的两性离子机理的第一个实例
5. First example of stepwise, zwitterionic mechanism for bicyclo2.2.1hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations [O] . Radomir Jasiński 2016

机译：1-丁基-3-甲基咪唑鎓阳离子催化双环2.2.1庚-5-烯（降冰片烯）形成过程的两性离子机理的第一个实例

PART I: BASE-HYDROLYSIS OF HALOLACTONES. THE MECHANISM OF KETONE FORMATION IN THE BICYCLO(2.2.1)HEPTYL SYSTEM. PART II. ACID-CATALYZED LACTONIZATION. ELECTROPHILIC REACTIVITY OF BICYCLO(2.2.2)OCT-5-ENE-2-CARBOXYLIC ACIDS.

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