Kinetic study of the reaction of ferrocenes and ferrocenium ions with ground and excited states of tris(2,2'-bypyridine)chromium ions and the preparation and homolysis of organocobalt complexes.

摘要

The kinetics of quenching of ;The preparations of a series of organocobalt complexes, RCo(Me;The unimolecular homolysis have been studied for some of these complexes. The Co-C bond energy is about 23 Kcal/mol for these complexes. The rates of the alkyl group transfer from CoL