High density polyethylene (HDPE)/poly(ethylene terephthalate) (PET) polymer blend studies related to recycling co-mingled plastics.

摘要

Polymer blends of virgin high density polyethylene (HDPE) and poly(ethylene terephthalate) (PET) were studied as an attempt to relate the microstructure to the mechanical properties of the blends. The virgin blends were prepared by extrusion and then injection molded into specimens for characterization. Two of the virgin blends were tested for possible compatibilization using a styrene-ethylene-butylene-styrene (SEBS) block copolymer. In addition, six blends of post-consumer resins (PCRs) of HDPE and PET were included in this work for comparison.;The moduli of the virgin blends showed positive deviation from those expected from the rule of mixtures. The synergism of the composite moduli can be explained partly by a Poisson's effect. Yield strengths of the blends molded at low injection chamber temperatures (200;Compatibilization appeared to be advantageous since it dramatically improved the impact strength of the virgin blends. SEM micrographs of impact fractured surfaces revealed that the improved adhesion from compatibilization and the presence of numerous uniaxially aligned PET filaments in the HDPE substrate can account for the significant increases in fracture resistance of the compatibilized blends.;Mechanical performance of the PCRs was inferior to that of the virgin blends. Aside from polymer degradation and contamination due to repeated processing and handling, absence of PET filaments and interfacial bonding could be responsible for the poor performance. Therefore, careful selection of processing conditions to minimize degradation and compatibilization of the PCRs would be recommended for improving the mechanical properties of the recycled plastics where this can be advantageous and cost effective.