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A high selectivity gas sensor based on a semi-permeable zeolite membrane.

机译:基于半渗透沸石膜的高选择性气体传感器。

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摘要

A solid-state sensor design is developed for the selective detection of different gaseous species. The sensor relies on a semi-permeable membrane made of zeolite. Zeolites are uniformly porous on a molecular scale allowing gases to be permitted or restricted from sensor interaction based on their kinetic molecular size. This principle will allow the sensor to react to a particular gas species without potential interactions from unwanted species.; The sensor is based on a solid-state electrochemical sensor with a zirconia electrolyte, but contains a unique platinum-zirconia composite electrode. This electrode is composed of finely intermixed phases that can be made planar to accommodate the zeolite membrane.; The sensor has been shown to be effective at detecting oxygen, nitric oxide and carbon dioxide at low concentrations. With the addition of the zeolite membrane, the response to carbon dioxide in a mixed atmosphere is diminished. Weakness in the sensor fabrication caused early failure of the sensor. Analysis of the sensor show that a viable membrane was likely produced, but it also infiltrated the sensor structure causing the premature failure.
机译:开发了一种固态传感器设计,用于选择性检测不同的气态物质。该传感器依靠由沸石制成的半透膜。沸石在分子规模上是均匀多孔的,允许基于其动力学分子大小来允许或限制气体与传感器的相互作用。该原理将使传感器能够对特定的气体种类做出反应,而不会与有害物质产生潜在的相互作用。该传感器基于带有氧化锆电解质的固态电化学传感器,但包含独特的铂-氧化锆复合电极。该电极由精细混合的相组成,这些相可以制成平面形状以容纳沸石膜。已经证明该传感器可有效检测低浓度的氧气,一氧化氮和二氧化碳。通过添加沸石膜,在混合气氛中对二氧化碳的响应减弱。传感器制造中的弱点导致传感器过早失效。对传感器的分析表明,可能会产生活膜,但也会渗入传感器结构,导致过早失效。

著录项

  • 作者

    Rauch, William L.;

  • 作者单位

    Georgia Institute of Technology.;

  • 授予单位 Georgia Institute of Technology.;
  • 学科 Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 2002
  • 页码 126 p.
  • 总页数 126
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 工程材料学;
  • 关键词

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