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Carbon Dioxide Activated Steel Slag as a Cementing Material.

机译:二氧化碳活化钢渣作为固井材料。

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摘要

Steel slag is a major by-product of the steel industry, with a production of nearly 300 kg for every tonne of steel produced. It has been conventionally used as an aggregate in road base construction, but this use has been limited due to the high free lime content, which causes volume expansion problems. This thesis explores the feasibility of using CO2 activation to eliminate free lime and develop strength for a steel slag-based building product. The CO2 activated steel slag has the potential to be used as cementing material to replace Ordinary Portland Cement (OPC) and to sequester carbon dioxide through activation. The technology can show numerous technical and environmental benefits, while minimizing the embodied energy in the final products.;Compressive strength and carbon uptake of compacts made of KOBM1, KOBM2, ladle and GGBF slag were evaluated in comparison with counterpart OPC compacts. KOBM slag showed the greatest potential, with compressive strength and carbon uptake values comparable to OPC. The microstructural change of carbon dioxide activated KOBM slag was assessed in detail by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). Its durability was also measured by the means of an accelerated water softening test. The wallboard made of KOBM slag bonded with sawdust was fabricated, and its mechanical performance was found to be competitive to commercial cement-based wall-boards. The research demonstrates that certain types of steel slags can be successfully activated by carbon dioxide in the production of commercial products to replace OPC.
机译:钢渣是钢铁工业的主要副产品,每生产一吨钢可产生近300公斤的产量。它通常被用作路基建设中的骨料,但是由于高的游离石灰含量限制了其使用,这会引起体积膨胀问题。本文探讨了使用CO2活化消除游离石灰并提高钢渣基建筑产品强度的可行性。 CO2活化的钢渣有潜力用作固井材料来代替普通的波特兰水泥(OPC)并通过活化隔离二氧化碳。该技术可以显示出众多的技术和环境效益,同时将最终产品中包含的能量降到最低。与相应的OPC压块相比,评估了由KOBM1,KOBM2,钢包和GGBF渣制成的压块的抗压强度和碳吸收率。 KOBM渣显示出最大的潜力,其抗压强度和碳吸收值可与OPC媲美。通过X射线衍射(XRD),热重分析(TGA)和扫描电子显微镜(SEM)详细评估了二氧化碳活化的KOBM炉渣的微观结构变化。还通过加速水软化测试来测量其耐久性。制作了用木屑与锯末粘合而成的墙板,发现其机械性能可与商用水泥基墙板相媲美。研究表明,在商业产品的生产中,某些类型的钢渣可以被二氧化碳成功活化,从而代替OPC。

著录项

  • 作者

    El-Baghdadi, Ahmed Hussein.;

  • 作者单位

    McGill University (Canada).;

  • 授予单位 McGill University (Canada).;
  • 学科 Engineering Civil.
  • 学位 M.Eng.
  • 年度 2012
  • 页码 103 p.
  • 总页数 103
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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