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Metal silicide nanowires for nanoscale contacts and polycrystalline silicon thin films for solar cells by metal-induced growth.

机译:通过金属诱导生长,用于纳米级触点的金属硅化物纳米线和用于太阳能电池的多晶硅薄膜。

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摘要

The metal-induced growth method (MIG) has been used to grow metallic nanowires for nanoscale interconnections and Si thin films for solar cell applications. Metal-induced growth (MIG) is a spontaneous reaction of metal and Si.; MIG nanowires were grown at 575 °C, which is the lowest nanowire growth temperature in the solid state. Three types of catalysts, such as Ni, Co, and Pd were demonstrated to establish the growth mechanism concluding that metal should be a major diffuser to grow nanowires. Ni-induced growth is the most successful to form nickel monosilicide (NiSi) nanowires, 20--100 nm in diameter and 1--10 mum in length. The nanowire growth mechanism is based on the formation of the NiSi phase and Ni diffuses inside the nanowire body as well as the bottom layer as shown by TEM studies. Nanowires are attractive 1-dimensional building blocks to use in nanoelectronics and nanoscale connections. It may be a breakthrough to the "Red Brick Wall", which is a potential barrier of device scaling. The MIG nanowires have been utilized to form a nanoscale interconnection in a tiny space-nanobridge. It differs from the conventional methods which are assisted by external factors, such as electric or magnetic field, and focused ion or electron beam lithography. This MIG nanobridge is independent from complex fabrication requirements. Electrical measurement was directly performed from the nanowire as-grown state and gave a metallic transport characteristic with a low resistance of 148 O. Resistivity of the NiSi nanowire was calculated to be 10.6 Om, close to the NiSi film. The self-assembled nanobridge is practical for use in nanoscale interconnection with a reduced thermal budget.; MIG poly-Si films were grown at 600--620 °C with 2--5 um thickness. Ni, Co, or Co coated Ni were used as a catalyst to provide a seed layer of NiSi2 and CoSi2. These catalysts form a good template to grow an epitaxial Si film due to their low lattice mismatch to Si by 0.4 % and 1.23 %, respectively. The MIG Si films were fabricated for solar cells. X-ray photoelectron spectroscopy investigation was performed to investigate the depth of the silicide layer. The formation of silicide phases was traced by X-ray diffraction. The grain size and surface morphology were studied by atomic force microscopy analysis. The Ni-induced case showed metal contamination of the Si film resulting in a poor Schottky junction. The Co-induced case was stable but the poly-Si grain size is small. The coated Ni case was motivated by taking advantage of large grain size by Ni and stability by Co. It enhanced the short circuit current density by one order higher than that of the single Co use. The Co coating successfully prevented Ni contamination and improved the quality of the Si film at the same time.
机译:金属诱导生长方法(MIG)已用于生长用于纳米级互连的金属纳米线和用于太阳能电池应用的Si薄膜。金属诱导的生长(MIG)是金属和Si的自发反应。 MIG纳米线在575°C下生长,这是固态下最低的纳米线生长温度。三种类型的催化剂(如Ni,Co和Pd)被证明建立了生长机理,从而得出结论,金属应该是生长纳米线的主要扩散体。镍诱导的生长最成功地形成直径为20--100 nm,长度为1--10微米的单硅化镍(NiSi)纳米线。纳米线的生长机理是基于NiSi相的形成,Ni会扩散到纳米线体内以及底层(如TEM研究所示)。纳米线是用于纳米电子学和纳米级连接的有吸引力的一维构建基块。这可能是“红砖墙”的突破,它是设备扩展的潜在障碍。 MIG纳米线已用于在微小的空间纳米桥中形成纳米级互连。它与传统方法不同,传统方法在外部因素(例如电场或磁场)以及聚焦离子或电子束光刻的帮助下进行。该MIG纳米桥独立于复杂的制造要求。从纳米线的生长状态直接进行电学测量,并给出了具有148 O低电阻的金属传输特性。NiSi纳米线的电阻率经计算为10.6 Om,接近NiSi膜。自组装的纳米桥可用于减少热预算的纳米级互连。 MIG多晶硅膜在600--620°C下生长,厚度为2--5微米。使用Ni,Co或涂覆有Co的Ni作为催化剂以提供NiSi 2和CoSi 2的种子层。这些催化剂形成良好的模板以生长外延硅膜,这是因为它们与硅的晶格失配率低,分别为0.4%和1.23%。制作了用于太阳能电池的MIG Si膜。进行X射线光电子能谱研究以研究硅化物层的深度。通过X射线衍射追踪硅化物相的形成。通过原子力显微镜分析研究了晶粒尺寸和表面形态。 Ni诱导的情况表明Si膜受到金属污染,从而导致肖特基结不良。 Co诱导的情况是稳定的,但是多晶硅的晶粒尺寸很小。镀镍外壳是通过利用镍的大晶粒尺寸和钴的稳定性而获得动力的。它使短路电流密度比单次使用钴提高了一个数量级。 Co涂层成功地防止了Ni污染并同时提高了Si膜的质量。

著录项

  • 作者

    Kim, Joondong.;

  • 作者单位

    State University of New York at Buffalo.;

  • 授予单位 State University of New York at Buffalo.;
  • 学科 Engineering Electronics and Electrical.; Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 2006
  • 页码 146 p.
  • 总页数 146
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 无线电电子学、电信技术;工程材料学;
  • 关键词

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