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Characterization of recycled paper mill sludge and evaluation of potential applications.

机译:再生造纸厂污泥的表征和潜在应用评估。

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This research addresses re-use of recycled paper mill sludge (RPS), a waste by-product of recycled paper manufacturing. The growth of the paper recycling industry over the past 15 years has led to ecological benefits; however it is estimated that over 9 million tonnes of sludge by-product are produced each year in North America, with limited use in beneficial applications.;Recycled paper mill sludges that represent a significant segment of the recycling industry were used in this work. Sludges were prepared using a novel kinetic de-watering system that dried and fiberized the material. The unique constitution of the dry sludge overcame constraints of failed utilization attempts of the past. Comprehensive physical and chemical characterization elucidated differences in the sludges based on generating process and raw furnish. Differences in organic content, fibre length, inorganic content and fibre chemistry were found to be strongly influenced by the recycling processes. Fibre contained in recycled newsprint manufacturing sludge had characteristics similar to TMP/mechanical fibre, while the fibre contained in recycled tissue manufacturing sludge were more similar to chemically prepared fibre.;Investigation into using the sludge as filler/reinforcing fibre in thermoplastic composites was carried out, as was an investigation into recovering a fibrous fraction for re-use in paper. The viability of using the recovered fibre portion in paper making is limited by its lack of bondability. This is caused by cell wall hornification and lack of bonding surface area resulting from the absence of fibrils. Sludge was incorporated successfully into thermoplastic composites displaying strength properties superior to the polymer matrix material. Flexural strengths were 50% higher, flexural moduli were over 100% higher and tensile moduli were 25--100% higher. Fibrous morphology, non-polar extractives, high volume packing and high intrinsic fibre strength contributed to ease of processability and superior performance. This application warrants further investigation based on economic viability and ecological benefits.
机译:这项研究针对的是回收造纸厂污泥(RPS)的再利用,RPS是回收造纸业的废物副产品。过去15年中,纸张回收行业的发展带来了生态效益;然而,据估计,北美每年产生超过900万吨的污泥副产品,在有益的应用中用途有限。这项工作使用了代表回收行业很大一部分的再生造纸厂污泥。使用新型的动力脱水系统制备污泥,该系统将物料干燥并纤维化。干污泥的独特构造克服了过去无法利用的限制。综合的物理和化学特性阐明了基于产生工艺和原料的污泥的差异。发现有机物含量,纤维长度,无机物含量和纤维化学性质的差异受到回收过程的强烈影响。再生新闻纸制造污泥中所含的纤维具有类似于TMP /机械纤维的特性,而再生纸巾制造污泥中所含的纤维与化学制备的纤维更相似。;进行了将污泥用作热塑性复合材料中的填料/增强纤维的研究。 ,以及对回收纤维部分再用于纸中的研究。在造纸中使用回收的纤维部分的可行性由于缺乏粘合性而受到限制。这是由于细胞壁角化和由于没有原纤维而导致的缺乏结合表面积引起的。污泥已成功掺入热塑性复合材料中,表现出优于聚合物基体材料的强度特性。弯曲强度高50%,弯曲模量高100%以上,拉伸模量高25--100%。纤维形态,非极性萃取物,高堆积率和高固有纤维强度有助于简化可加工性和卓越性能。此应用程序需要根据经济可行性和生态效益进行进一步研究。

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