文摘
英文文摘
Pat Ⅰ EIS study of transport of Water and Cl- in organic coatings
Chapter 1 literature review
1.1 Protection mechanism of organic coatings
1.2 factors affecting the protection properties oforganic coatings and degradation mechanism of organic coated metals
1.3 Pigmentation of organic coatings for corrosion protection
1.4 Application of electrochemical impedance spectroscopy (EIS)
1.5 Water uptake in organic coatings
1.6 ions transport in coatings
1.7 Modern testing methods for coated metals
1.8 Objectives of the present work
References
Chapter 2 Modeling of Fickian behavior for water diffusion in organic coatings
2.1 linear fickian diffusion[1]
2.2 Non-linear Fickian diffusion
References
Chapter 3 Impedance Models of Epoxy Coated Aluminum Alloys in NaCl Solution
3.1 Experimentals
3.2 Results and discussion
3.4 Conclusions
References
Chapter 4 Transport Behaviors of Corrosive Species and Degradation Mechanism of Epoxy Coated Aluminum Alloys in NaCl Solution
4.1 Experimentals
4.2 Water uptake and diffusion of Cl- ion in epoxy coatings
4.3 Ageing performance of coated metals
4.4 OCP of the electrode system
4.5 Conclusions
References
Chapter 5 Influences of coating thickness, pigmentation, and NaCl concentration in solution on coatings behaviors
5.1 Experimentals
5.2 Effect of coating thickness
5.3 Effect of pigmentation by red iron oxide
5.4 Effect of NaCl concentration
5.5 conclusions
References
Part Ⅱ Applications of EIS in kinetics studies of irreversible electrode reactions
Chapter 6 Oxygen Evolution Reaction on IrO2-based DSA Type Electrodes: Mathematical Modeling of Tafel Lines and EIS
6.1 Experimentals
6.2 Results and discussion
6.3 Conclusion
Appendix:
References
Chapter 7 Kinetics Investigation of H2/CO Electrooxidation in PEFCs by the Combined Use of Equivalent Circuit Models and Mathematical Modeling of Faradaic Impedance
7.1 Theoretical backgrounds
7.2 Experimentals
7.3 Results and discussion
7.4 Summaries
References
Acknowledgement
Publications in post-doctoral period
Publications in Ph.D. course period
Biography
