第一个书签之前
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致谢
第一章 文献综述
引言
第一节 胺与烯烃的氢胺化反应研究进展
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第二节 芳胺和烯烃的氢烷基化反应研究进展
第三节立题思想
参考文献
[1] Recent reviews on hydroamination: (a) Huang, L
[2] Recent reviews on hydroaminomethylation (hydro
[3] Recent reviews on reductive amination of aldeh
[4] (a) Jain, P.C.; Kapoor, V.; Anand, N.; Ahmad,
[5] For reviews on hydroarylation, see: (a) Boorma
[6] (a) Friedel, C.; Crafts, J. M. J. Chem. Soc. 1
[7] March, J. Advanced Organic Chemistry: Reaction
[8] (a) Nishina, N.; Yamamoto, Y. Top. Organomet.
[9] (a) Hong, S.; Marks, T. J. Acc. Chem. Res. 200
[10] (a) Reznichenko, A. L.; Hultzsch, K. C. Top.
[11] Howk, B. W.; Little, E. L.; Scott, S. L.; Whi
[12] Brinkmann, C.; Barrett, A. G. M.; Hill, M. S.
[13] Li, Y.; Marks T. J.; Organometallics 1996, 15
[14] Ryu, J.-S.; Li, G. Y.; Marks, T. J. J. Am. Ch
[15] Walsh, P. J.; Baranger A. M.; Bergman R. G. J
[19] Mayur, J. B.; Nitin, S. N.; Malhari, D. B.; B
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参考文献
第三章[Ph3C][B(C6F5)4]催化芳胺与烯烃的氢烷基化反应
第一节[Ph3C][B(C6F5)4]催化芳胺与烯烃氢烷基化反应的条件优化
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第二节[Ph3C][B(C6F5)4]催化芳胺与烯烃氢烷基化反应的底物拓展
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第三节[Ph3C][B(C6F5)4]催化芳胺与烯烃氢烷基化反应的动力学研究
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4.3.2 乙烯基吡啶与胺分子间氢胺化反应产物的表征数据
6-methyl-1-(2-(pyridin-2-yl)ethyl)-1,2,3,4-tetrah
6-methyl-1-(2-(pyridin-4-yl)ethyl)-1,2,3,4-tetrah
1-(2-(pyridin-2-yl)ethyl)-1,2,3,4-tetrahydroquino
1-(2-(pyridin-4-yl)ethyl)-1,2,3,4-tetrahydroquino
1-(2-(pyridin-2-yl)ethyl)indoline (3a) 1H NMR (40
1-(2-(pyridin-4-yl)ethyl)indoline (3b) 1H NMR (40
5-bromo-1-(2-(pyridin-2-yl)ethyl)indoline (4a) 1H
5-bromo-1-(2-(pyridin-4-yl)ethyl)indoline (4b) 1H
2-methyl-1-(2-(pyridin-2-yl)ethyl)indoline (5a) 1
2-methyl-1-(2-(pyridin-4-yl)ethyl)indoline (5b) 1H
2-phenyl-1-(2-(pyridin-2-yl)ethyl)indoline (6a) 1
2-phenyl-1-(2-(pyridin-4-yl)ethyl)indoline (6b) 1
4-(2-(pyridin-2-yl)ethyl)-3,4-dihydro-2H-benzo[b]
4-(2-(pyridin-4-yl)ethyl)-3,4-dihydro-2H-benzo[b]
N-ethyl-N-(2-(pyridin-2-yl)ethyl)aniline (9a) 1H
N-ethyl-N-(2-(pyridin-4-yl)ethyl)aniline (9b) 1H
2-(2-(pyridin-2-yl)ethyl)-1,2,3,4-tetrahydroisoqu
2-(2-(pyridin-4-yl)ethyl)-1,2,3,4-tetrahydroisoqu
2-(2-(piperidin-1-yl)ethyl)pyridine (11a)[ ] 1H N
2-(2-(piperidin-1-yl)ethyl)pyridine (11b)[3] 1H N
2-(2-(pyrrolidin-1-yl)ethyl)pyridine (12a)[3] 1H
4-(2-(pyrrolidin-1-yl)ethyl)pyridine (12b)[3] 1H
4-(2-(pyridin-2-yl)ethyl)morpholine (13a)[3] 1H NM
4-(2-(pyridin-4-yl)ethyl)morpholine (13b)[3] 1H N
N-benzyl-N-methyl-2-(pyridin-2-yl)ethan-1-amine (
N-benzyl-N-methyl-2-(pyridin-4-yl)ethan-1-amine (
N-benzyl-N-(2-(pyridin-2-yl)ethyl)aniline (15a) 1H
N-benzyl-N-(2-(pyridin-4-yl)ethyl)aniline (15b) 1H
N,N-dibenzyl-2-(pyridin-2-yl)ethan-1-amine (16a)
N,N-dibenzyl-2-(pyridin-4-yl)ethan-1-amine (16b)
N-(2-(pyridin-2-yl)ethyl)aniline (17a) 1H NMR (40
N,N-bis(2-(pyridin-2-yl)ethyl)aniline (17b) 1H NM
4-methyl-N-(2-(pyridin-2-yl)ethyl)aniline (18a)[2
4-methyl-N,N-bis(2-(pyridin-2-yl)ethyl)aniline (1
4-methoxy-N-(2-(pyridin-2-yl)ethyl)aniline (19a)[
4-methoxy-N,N-bis(2-(pyridin-2-yl)ethyl)aniline (
4-chloro-N-(2-(pyridin-2-yl)ethyl)aniline (20a) 1H
4-chloro-N,N-bis(2-(pyridin-2-yl)ethyl)aniline (2
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1H, 1H GCOSY (400 MHz / 400 MHz, CDCl3) [selected
1H, 13C GHSQC (400 MHz / 100 MHz, CDCl3): δ 1H / δ
6,8-bis(1-phenylethyl)-1,2,3,4-tetrahydroquinoline
N-ethyl-2-(1-phenylethyl)aniline (6c). 1H NMR (40
N-phenyl-2-(1-phenylethyl)aniline (6d). 1H NMR (4
2-methyl-8-(1-phenylethyl)-1,2,3,4-tetrahydroquin
6-bromo-8-(1-phenylethyl)-1,2,3,4-tetrahydroquino
6-methoxy-8-(1-phenylethyl)-1,2,3,4-tetrahydroquin
6-methyl-8-(1-phenylethyl)-1,2,3,4-tetrahydroquin
7-(1-phenylethyl)indoline (6i). 1H NMR (400 MHz,
2-methyl-7-(1-phenylethyl)indoline (6j). 1H NMR (4
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2-phenyl-7-(1-phenylethyl)indoline (6k). 1H NMR (
5-bromo-7-(1-phenylethyl)indoline (6l). 1H NMR (4
5-methyl-7-(1-phenylethyl)indoline (6m). 1H NMR (4
4-methyl-2,6-bis(1-phenylethyl)aniline (6n).[2] 1
2,4,6-tris(1-phenylethyl)aniline (6o). 1H NMR (40
4-methoxy-N,N-dimethyl-2-(1-phenylethyl)aniline (6
N,N-dimethyl-3-(1-phenylethyl)-[1,1'-biphenyl]-4-
N,N-dimethyl-6-(1-phenylethyl)-2,3-dihydro-1H-ind
N,N,4-trimethyl-2-(1-phenylethyl)aniline (6u). 1H
N,N,2-trimethyl-6-(1-phenylethyl)aniline (6v). 1H
8-(1-(4-methoxyphenyl)ethyl)-6-methyl-1,2,3,4-tet
6-methyl-8-(1-(p-tolyl)ethyl)-1,2,3,4-tetrahydroq
8-(1-([1,1'-biphenyl]-4-yl)ethyl)-6-methyl-1,2,3,4
8-(1-(4-(tert-butyl)phenyl)ethyl)-6-methyl-1,2,3,4
8-(1-(4-fluorophenyl)ethyl)-6-methyl-1,2,3,4-tetr
8-(1-(4-chlorophenyl)ethyl)-6-methyl-1,2,3,4-tetr
8-(1-(4-bromophenyl)ethyl)-6-methyl-1,2,3,4-tetra
6-methyl-8-(1-(m-tolyl)ethyl)-1,2,3,4-tetrahydroq
13C{1H} NMR (100 MHz, CDCl3): 146.1, 140,2, 138.5,
8-(1-(3-fluorophenyl)ethyl)-6-methyl-1,2,3,4-tetra
8-(1-(3-chlorophenyl)ethyl)-6-methyl-1,2,3,4-tetr
8-(1-(3-bromophenyl)ethyl)-6-methyl-1,2,3,4-tetra
6-methyl-8-(1-(o-tolyl)ethyl)-1,2,3,4-tetrahydroq
8-(1-(2-fluorophenyl)ethyl)-6-methyl-1,2,3,4-tetra
8-(1-(2-chlorophenyl)ethyl)-6-methyl-1,2,3,4-tetr
8-(1-(2-bromophenyl)ethyl)-6-methyl-1,2,3,4-tetrah
6-methyl-8-(2-phenylpropan-2-yl)-1,2,3,4-tetrahyd
8-(bicyclo[2.2.1]heptan-2-yl)-6-methyl-1,2,3,4-te
8-(cyclohex-2-en-1-yl)-1,2,3,4-tetrahydroquinolin
8-(octan-2-yl)-1,2,3,4-tetrahydroquinoline (7t).
8-(hexan-2-yl)-1,2,3,4-tetrahydroquinoline (7u).
6-methyl-8-(1-phenylpropyl)-1,2,3,4-tetrahydroqui
N-(2-(bicyclo[2.2.1]heptan-2-yl)-4-methylphenyl)a
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攻读硕士期间本人出版或公开发表的论著、论文
附录
Abbreviations and Acronyms
Abbreviations
Acronyms
Me
methyl
Ph
phenyl
Pr
propyl
Ar
aryl
Ac
acetyl
Bu
butyl
hex
hexane
THF
tetrahydrofuran
tol
toluene
s
singlet
d
doublet or day(s)
t
triplet
q
quartet
ppm
parts per million
oC
centigrade degree
mmol
millimole
p
para
i
iso
n
NMR
nuclear magnetic resonance
ESI-MS
electrospray ionization mass spectrometry
GC-MS
gas chromatography mass spectrometry
HR-MS
high resolution mass spectrometry
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核磁谱图
致谢
光阴似箭,一转眼我已经在苏州大学待了近三个年头,这三年的科研生涯是我人生中极其珍贵的时光。在这段日子
感谢分析测试中心的赵彦伟老师在样品高分辨测试上的帮助、感谢王璐老师、朱慧芳等老师在样品核磁检测上的帮
感谢同课题组各个实验室师兄师姐师弟师妹的帮助,感谢你们在我实验窘迫时慷慨解囊,在我生活糟心时给我希望
感谢舍友在生活上给予我的关心与帮助。最后感谢爷爷奶奶、爸爸妈妈对我的包容和支持,使我能安心工作学习。