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Molecular machine, light-powered chiral molecular motor: its chemistry and rotation mechanism

机译:分子机器,光动力手性分子马达:其化学性质和旋转机理

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One of the ultimate research goals of material of material science would be the construction of molecular machines, where one molecule mechanically works as a machine by external energy sources. As such molecular machines, some analyogues of rotors, gears, switches, shuttles, turnstiles, and ratchets have been proposed. However, molecular motors with power-mechanism have never been made, although biological motors are common in living things. In addition, in the molecular motors, it has remained very difficult to convert energy into unidirectional rotatory motion. Namely in the construction of molecular motors, it was a major problem to control the direction of rotation. We report here the first construction of a light-powered chiral molecular motor, which photochemically rotates only in one-direction rflecting the chirality of the motor molecule. The motor rotation is controlled by the irradiation of hight and molecular chirality.
机译:材料科学的最终研究目标之一是构建分子机器,其中一个分子通过外部能源机械地充当机器。作为这样的分子机器,已经提出了一些转子,齿轮,开关,梭子,旋转门和棘轮的类似物。然而,尽管生物电动机在生物中很常见,但从未制造出具有动力机制的分子电动机。另外,在分子电动机中,将能量转换为单向旋转运动仍然非常困难。即,在分子电动机的构造中,控制旋转方向是主要问题。我们在这里报告光动力手性分子电动机的第一个结构,该结构仅在一个方向上发生光化学旋转,从而反映了电动机分子的手性。电动机的旋转是通过高手性和分子手性的照射来控制的。

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