Thermal Investigation of IA Metal Perchlorate

摘要

Fuel/Oxide mixtures are typical priming composition of electro-explosiverndevices ,inorganic salts for powder oxidizer, such as potassium perchloraternetc., are important for application a pyrotechnic formulations, In this work, thernthermal behaviors of three metal perchlorate, LiClO4, NaClO4 and KClO4 arerninvestigated by DTA/TG. And the kinetic parameters of decomposition will alsornevaluate using non-isothermal techniques, The decomposition temperature arernfound shift to high temperature by increasing the diameter of metal atom, therndata of thermal behaviors and the kinetic parameters for decomposition arernquite useful on the pyrotechnic applications.