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Application of Composite Hydrosol as Anti-felting Agent

机译:复合水溶胶作为防毡剂的应用

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The alkoxysilane and TiO<,2> sols were prepared by the sol-gel method using tetrabutyl titanate (TTB) and γ-glycidyloxypropyltrimethoxysilane (GPTMS) as precursors, respectively. And the composite sol was prepared by the blend of alkoxysilane and TiO<,2> sol. FTIR, XRD and PCS were used to characterize sols. The influence of the TiO<,2> content in the composite sol on anti-felting property of wool fabric was investigated according to I. W. S TM31. Results show that the size of the alkoxysilane, TiO<,2> and their hybrid particles in sol are about 15, 25 and 27nm, respectively. SiO-Ti bond forms in the powder of the composite sol. The crystalline structure of TiO<,2> powders is identified as the amorphous oxide network. In contrast with alkoxysilane sol, composite sol can lower the curing temperature efficiently when TiO<,2> content is 2.7%, and area shrinkage of treated fabric is 1.9%.
机译:分别通过钛酸四丁酯(TTB)和γ-环氧丙氧基丙基三甲氧基硅烷(GPTMS)作为前体,通过溶胶-凝胶法制备烷氧基硅烷和TiO,2溶胶。然后通过烷氧基硅烷和TiO 2溶胶的共混物制备复合溶胶。 FTIR,XRD和PCS用于表征溶胶。根据I.W.S TM31,研究了复合溶胶中TiO 2含量对羊毛织物防缩毛性能的影响。结果表明,烷氧基硅烷,TiO 2和它们的杂化颗粒在溶胶中的尺寸分别为约15、25和27nm。 SiO-Ti键在复合溶胶的粉末中形成。 TiO 2粉末的晶体结构被确定为非晶氧化物网络。与烷氧基硅烷溶胶相反,当TiO 2含量为2.7%且处理的织物的面积收缩率为1.9%时,复合溶胶可有效降低固化温度。

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