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Study on the Cure Kinetics of Middle Temperature Curing 3234 Epoxy Resin System

机译:中温固化3234环氧树脂体系的固化动力学研究

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摘要

The cure kinetics of middle temperature curing 3234 epoxy resin was investigated under both isothermal and dynamic curing conditions by Differential Scanning Calorimetry (DSC) technique. The kinetic equations for isothermal and dynamic curing were established respectively by analyzing experimental data obtained from DSC . By following the temperature procedure of the standard cure cycle of the resin system, the validity of the cure kinetic equations was verified by means of determining the residual heat of reaction of samples from different stages of the cure cycle. Results showed that the cure kinetics under both isothermal and dynamic conditions could be described by the autocatalytic kinetic model. Predictions by the kinetic equation for dynamic curing agreed well with the experimental results.
机译:通过差示扫描量热法(DSC)研究了在等温和动态固化条件下中温固化3234环氧树脂的固化动力学。通过分析DSC的实验数据,分别建立了等温固化和动态固化的动力学方程。通过遵循树脂体系标准固化周期的温度程序,通过确定固化周期不同阶段的样品反应剩余热量,验证了固化动力学方程的有效性。结果表明,在等温和动态条件下的固化动力学都可以用自催化动力学模型来描述。通过动力学方程对动态固化的预测与实验结果吻合得很好。

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