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Low Temperature Optical Absorption by Magnons In KniF_3 and NiO Single-Crystals

机译:磁振子在KniF_3和NiO单晶中的低温光吸收

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摘要

OPtical absorption spectra of KNiF_3 and NiO stoichiometric single-crystals were measured at 5 K in the range from 4000 to 50000 cm~-1. The observed bands are interpreted based on the energy levels diagram for Ni~2+ (3d~8) ion in a cubic crystal field. The crystal-field parameter Dq is equal to 766 cm~-1 in KNif_3 and 890 cm~-1 in NiO. Particular attention is paid to the band due to the magnetic-dipole ~3A_2g(F)->~3T_2g(F) transition, located at 7700 cm~-1 in KNiF_3 and at 8900 cm~-1 in NiO. We show that the energy difference between the two peakds, located at the low energy side of the band, is related to the zone-center (k=0) one-magnon energy, so that the low-energy peak is attributed to the pure exciton transition, whereas the high-energy peak to the exciton-magnon excitation. The estiamted one-magnon energies are 25+-5 cm~-1 in KNiF_3 and 39+-3 cm~-1 in NiO.
机译:在5 K下在4000至50000 cm〜-1范围内测量KNiF_3和NiO化学计量单晶的光学吸收光谱。根据立方晶场中Ni〜2 +(3d〜8)离子的能级图解释观察到的能带。晶体场参数Dq在KNif_3中等于766 cm〜-1,在NiO中等于890 cm〜-1。由于磁偶极子〜3A_2g(F)->〜3T_2g(F)跃迁而特别引起注意,该跃迁在KNiF_3中位于7700 cm〜-1,在NiO中位于8900 cm〜-1。我们表明,位于峰的低能侧的两个峰之间的能量差与区域中心(k = 0)一磁子能有关,因此,低能峰归因于纯激子跃迁,而高能峰达到激子-磁振子激发。在KNiF_3中,估计的一磁子能量为25 + -5 cm〜-1,在NiO中为39 + -3 cm〜-1。

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