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Fabrication of Biodegradable Low Elastic Porous Mg-Zn-Mn-HA Alloy by Spark Plasma Sintering for Orthopaedic Applications

机译:通过用于整形外科应用的火花等离子体烧结可生物降解的低弹性多孔Mg-Zn-Mn-HA合金的制备

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In the present research work, porous Mg-Zn-Mn-HA alloy was successfully fabricated by mechanical alloying of magnesium (Mg), manganese (Mn), zinc (Zn), and hydroxyapatite (HA) powders followed by consolidation using Spark Plasma Sintering technique. The microstructure, surface topography, and element composition of the Mg-Zn-Mn-HA alloy was investigated using optical microscope, field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The micro-hardness of the specimens was measured on a Vickers hardness tester. The microstructure and FESEM examination of the compact revealed that the alloy distinctly shows the porosities in the microstructure. It was observed that complex reactions between HA and alloy elements occurred during the sintering process of Mg-Zn-Mn-HA alloy and biocompatible phases such as Manganese Oxide ((MnO)_(0.441) (CaO)_(0.559)), Mgo.97 Zn_(0.03), Manganese Phosphide (Mn_(1.9) P), Calcium Manganese Oxide (Ca2 Mn8 O_(16)), and Zincite (ZnO2) were generated in the compact, which is beneficial to form apatite and improved the bioactivity of the alloy for osseiointegartion. The fabricated Mg-Zn-Mn-HA alloy exhibits maximum micro-hardness (-97 HV), which is very high value as compared to the alloys reported in literature. Based on these above observations, it is expected that the as-fabricated Mg-Zn-Mn-HA alloy is suggested for orthopaedic applications.
机译:在本研究工作中,通过镁(Mg),锰(Mn),锌(Zn)和羟基磷灰石(HA)粉末的机械合金化成功制造多孔Mg-Zn-Mn-HA合金,然后使用火花等离子体烧结固结技术。使用光学显微镜,场发射扫描电子显微镜和能量分散X射线光谱研究Mg-Zn-Mn-HA合金的微观结构,表面形貌和元件组合物。在维氏硬度测试仪上测量标本的微硬度。紧凑的微观结构和FESEM检查揭示了合金明显地显示了微观结构中的孔隙率。观察到,在Mg-Zn-MN-HA合金和生物相容性阶段的烧结过程中,在Mg-Zn-MN-HA合金和生物相容性相的烧结过程中发生复合反应,例如氧化锰((MNO)_(0.441)(CaO)_(0.559)),MgO .97 Zn_(0.03),磷化锰(MN_(1.9)P),氧化钙(Ca2mN8 O_(16))和锌钛矿(ZnO2)在紧凑的情况下产生,这有利于形成磷灰石并改善生物活性综合症的合金。制造的Mg-Zn-Mn-HA合金表现出最大的微硬度(-97HV),与文献中报道的合金相比,值非常高。基于上述观察结果,预计为整形外科应用提出了制造的Mg-Zn-Mn-HA合金。

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