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Nano-scale phenomena and applications in polymer processing

机译:纳米规模现象和聚合物加工中的应用

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This paper shows nano-scale phenomena relevant to polymer processing. It is organized in foursections. It first addresses the dynamics of polymer chains in confined geometries and shows that in contrary to intuition one may have, polymer chains may diffuse much faster in confined geometries than in the bulk. It then attempts toshade lights on extruder processing of polymer nanocomposites. Understanding of the dynamics of polymer chains in confined geometries helps to achieve the goal. The third section is concerned with the use of nano-objects as nano-reactors. An example is given to show how one may take the advantage of nano-reactors to improve reaction yield and/or reaction selectivity. The last section deals with reaction kinetics at polymer-polymer interfaces, a very important issue in reactive polymer blending processes.
机译:本文显示了与聚合物加工相关的纳米级现象。它是四分之一的组织。它首先解决了狭窄的几何形状中聚合物链的动态,并表明,与直觉中可能具有相反,聚合物链可以在狭窄的几何形状中扩散得比体积更快。然后,它试图在聚合物纳米复合材料的挤出机加工上进行Toshade灯。理解受限几何形状中聚合物链的动态有助于实现目标。第三部分涉及使用纳米物体作为纳米反应器。给出了一个例子来展示如何采取纳米反应器的优点以改善反应产率和/或反应选择性。最后一节涉及聚合物 - 聚合物界面的反应动力学,这是反应性聚合物混合过程中非常重要的问题。

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