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Mineralization rates of hexadecane and pyrene during active composting of contaminated soil

机译:污染土壤活性堆肥期间十六烷和芘的矿化率

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Active composting of soil is the term used to describe processes whereby soil is mixed with large amounts of biodegradable organic material resulting in greatly increased microbial activity due to degradation of the organic matter. Active compositing of contaminated soil has proven to be an effective means of bioremediation for a wide range of contaminants [1-3] and is especially effective when dealing with weathered hydrocarbon-contaminated soils [4]. Polycyclic aromatic hydrocarbons (PAHs) containing four or more condensed rings are usually relatively recalcitrant [5]. Composting has been specifically suggested for treatment of such PAHs in contaminated soil since they may be cometabolized in the presence of more easily degraded compounds [6]. However, little is known about the fate of PAHs during composting. Although chemical analysis frequently shows their disappearance, they may become unextractable, converted to other chemical forms or be mineralized. If mineralization does occur, rates must be determined so that the process can be better compared to others. In addition, mineralization rates can be used in mathematical modeling of the process in order to better explain the mechanisms governing it. Significant mineralization rates have been reported for PAHs having more than 4 fused rings during composting of municipal waste [7]. The addition of mature compost to soil spiked with an anthracene (3-rings) and hexadecane-contaminated soil has resulted in the mineralization of these contaminants [8]. However, no data are available for mineralization rates during active composting of soil.
机译:活跃的土壤堆肥是用于描述土壤与大量可生物降解的有机材料混合的过程的术语,导致由于有机物质的降解导致的微生物活性大大增加。污染土壤的活性合成已被证明是各种污染物的生物修复的有效手段[1-3],在处理风化的碳氢化合物污染的土壤时特别有效[4]。含有四个或更多个冷凝环的多环芳烃(PAHS)通常是相对rolalcrator的[5]。已经特别建议堆肥用于治疗污染的土壤中这种PAHS,因为它们可以在更容易降解的化合物存在下进行复合[6]。然而,在堆肥期间,关于PAH的命运很少。虽然化学分析经常显示出他们的消失,但它们可能会变得无法伸出的,转化为其他化学形式或矿化。如果发生矿化,则必须确定速率,以便与他人相比,该过程可以更好。此外,矿化率可用于该过程的数学建模,以便更好地解释控制它的机制。据报道,在城市垃圾堆堆肥期间具有超过4个融合环的PAH的显着的矿化率[7]。将成熟的堆肥添加到用蒽(3环)和十六烷污染的土壤掺入土壤,导致这些污染物的矿化[8]。但是,在接壤的活跃堆肥期间没有任何数据可用于矿化率。

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