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Synthesis and Performance of 4,5-Dicyano-2H-1,2,3-triazole

机译:4,5-二氰基-2H-1,2,3-三唑的合成与性能

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摘要

4,5-Dicyano-2H-1,2,3-triazole(DCT) was synthesized with Diaminomaleodinitrile as the raw material.The structure of DCT was charactered by IR,1H NMR, 13C NMR and EA.Its synthesis process was optimized.The thermal stability of DCT was investigated by TG-DSC technique.The kinetic parameters including activation energy and pro-exponential factor were calculated by Kissinger equation.Its hygroscopicity, impact and friction sensitivity were also measured.4,5-dicyano-2H-l,2,3-triazole has potential application prospect as environmentally friendly gas generant, explosive and solid propellant.
机译:以二氨基马来腈为原料合成了4,5-二氰基-2H-1,2,3-三唑(DCT)。通过IR,1H NMR,13C NMR和EA对DCT的结构进行了表征,并对其合成工艺进行了优化。用TG-DSC技术研究了DCT的热稳定性,用Kissinger方程计算了包括活化能和指数因子在内的动力学参数,并测定了其吸湿性,冲击性和摩擦敏感性.4,5-dicyano-2H-l ,2,3-三唑作为环境友好的气体发生剂,爆炸物和固体推进剂具有潜在的应用前景。

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