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Synchronization of a DSC with NIR-LEDs: a Simple Way to Photo-DSC

机译:DSC与NIR-LED的同步:光DSC的简单方法

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Photopolymers have received big interest in coating sciences. Quantitative knowledge of reactivity plays one major role to characterize such polymer systems. There are several methods available describing the kinetics of photopolymers operating according to a mechanism in which reaction heat would be released during crosslinking. From this point of view, Differential Scanning Calorimetry (DSC) can be used to determine the reaction heat released upon exposure with light generated either in the UV, visible or near infrared (NIR). Thus, coupling of the DSC with a lamp and synchronization of the begin and the end of exposure opens the possibility to study online photoinduced crosslinking of olefins and epoxies. A commercial solution has been already existing for synchronization between DSC and UV source. Nevertheless, it has not been described a general coupling of the DSC with light sources selected from LEDs or alternative exposure sources operating in the visible or near infrared (NIR). Thus, we describe a hardware and software solution in which nearby every light source can be integrated and synchronized with the DSC.
机译:光敏聚合物在涂料科学领域引起了极大的兴趣。反应性的定量知识在表征这类聚合物体系中起着主要作用。有几种可用的方法描述了根据在交联过程中会释放反应热的机理操作的光敏聚合物的动力学。从这个角度来看,差示扫描量热法(DSC)可用于确定暴露于紫外线,可见光或近红外(NIR)中产生的光时释放的反应热。因此,DSC与灯的耦合以及曝光开始和结束的同步开启了研究在线光引发的烯烃和环氧树脂交联的可能性。已经存在用于DSC和UV源之间同步的商业解决方案。然而,尚未描述DSC与选自LED或在可见或近红外(NIR)中操作的替代曝光源的光源的一般耦合。因此,我们描述了一种硬件和软件解决方案,其中附近的每个光源都可以集成并与DSC同步。

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