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Modeling and optimization of struvite precipitation process for phosphorus recovery from wastewater

机译:鸟粪石沉淀法从废水中回收磷的建模与优化

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The recovery of phosphorus from wastewater following struvite precipitation pathway can provide a viable and sustainable source for phosphorus. This pathway is important because current phosphorus ore reserves are expected to be exhausted within the next few decades, or, the recovery from the ores will become more costly. However, the recovery of phosphorus from wastewater is not straightforward due to the complexities arising from the number of variables and chemistry involved with the precipitation of phosphorus as struvite. Modeling the dynamic nature of the crystallization phenomenon appears to be the method of choice to control the process. In this study, a dynamic control model for phosphorus recovery process via struvite crystallization was developed. This model incorporated both chemistry and control software, and was used to increase the efficiency and ease of process operation of a pilot-scale fluidized crystallizer. This process model was the basis of an automatic controller that had the capability to manipulate flows and chemical additions, and thereby control the system at a desired set point. The control model was then used as a prediction tool to determine conditions that influence the supersaturation ratio — the primary control parameter — of the process.
机译:通过鸟粪石沉淀途径从废水中回收磷可以为磷提供可行和可持续的来源。该途径之所以重要,是因为目前的磷矿石储量有望在未来几十年内耗尽,否则从矿石中回收的成本将会更高。然而,由于变量的数量和与磷矿作为鸟粪石的沉淀有关的化学反应的复杂性,从废水中回收磷并不是一件容易的事。对结晶现象的动态性质进行建模似乎是控制过程的首选方法。在这项研究中,建立了通过鸟粪石结晶回收磷的动态控制模型。该模型结合了化学和控制软件,用于提高中试规模化流化结晶器的效率和工艺操作的简易性。该过程模型是自动控制器的基础,该自动控制器具有操纵流量和化学添加物的能力,从而可以将系统控制在所需的设定点。然后,将控制模型用作预测工具,以确定影响过程过饱和率(主要控制参数)的条件。

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