New Ionic Liquids containing Fluorosulfonyl(trifluoromethylsulfonyl)amide and 5- Phosphoniaspiro 4.4 nonan

机译：含氟磺酰基（三氟甲基磺酰基）酰胺和5-膦酰螺4.4壬烷的新型离子液体

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New room temperature ionic liquids (RTILs) containing phosphoniaspiro[4.4]nonan (PS_(4,4)~+) could be obtained by selecting an amide anion with structural asymmetry such as fluorosulfonyl (trifluoromethylsulfonyl) amide (FTA~). PS_(44)~+ could not form RTILs with another amide anion such as FSA" ([(FSO_2)_2N]~-, and TFSA~- ([(CF_3SO_2)_2N]~-), which indicated that the structural asymmetry in an anion effectively decreasing the melting point of symmetric phosphonium such as PS_(4,4)~+.

机译：通过选择具有结构不对称性的酰胺阴离子，例如氟磺酰基（三氟甲基磺酰基）酰胺（FTA〜），可以得到含有磷烟酰胺[4.4]壬南（PS_（4,4）〜+）的新型室温离子液体（RTIL）。 PS_（44）〜+无法与其他酰胺阴离子如FSA“（[（FSO_2）_2N]〜-和TFSA〜-（[（CF_3SO_2）_2N]〜-）形成RTIL，这表明在结构上不对称有效降低对称phospho（如PS_（4,4）〜+）熔点的阴离子。

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《International symposium on molten salts and ionic liquids;Electrochemical Society meeting》|2010年|p.35-40|共6页
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H. Matsumoto; T. Umecky; S. Tsuzuki;
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中图分类电化学工业;
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4. New Ionic Liquids containing Fluorosulfonyl(trifluoromethylsulfonyl)amide and 5- Phosphoniaspiro 4.4 nonan [C] . H. Matsumoto, T. Umecky, S. Tsuzuki International symposium on molten salts and ionic liquids . 2010

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New Ionic Liquids containing Fluorosulfonyl(trifluoromethylsulfonyl)amide and 5- Phosphoniaspiro 4.4 nonan

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