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Simulation of a tubular reactor for waste oxidation

机译:废物氧化管式反应器的模拟

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摘要

The thermal oxidation of organic waste in supercritical water is now a well-known process in several laboratories. The purpose of this work is to model a tubular reactor for supercritical water oxidation (S.C.W.O.). This program makes an assumption of one-dimensional flow. HOwever, several thermal boundary conditions were used (adiabatic reactor, constant heat coefficient, constant heat flux). Different products for which reaction kinetics are known from the literature (acetic acid, methane, methanol, ammoniac, pyridine, hydrogen...) were tested. For each substance, the concentration and temperatures profiles along the reactor axis were determined. Hence, the ignition temperature of the reaction can be calculated and are able to determine the final temperature and conversion.
机译:超临界水中有机废物的热氧化现在是几个实验室中的知名过程。本作作品的目的是为超临界水氧化的管状反应器进行模拟(S.C.O.)。该程序假设一维流。然而,使用了几种热边界条件(绝热反应器,恒定热系数,恒定热量)。测试了来自文献(乙酸,甲烷,甲醇,氨基,吡啶,氢气......)中已知的不同产品。对于每种物质,确定沿反应器轴线的浓度和温度曲线。因此,可以计算反应的点火温度并能够确定最终温度和转化。

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