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Dielectric and Mechanical Properties Evaluation of Polypropylene Containing Nitride-based Nanoparticles

机译:含氮化物基聚丙烯纳米粒子的介电和力学性能评估

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Polypropylene (PP) which is recyclable and easy to process, has the potential to be a promising alternative for conventional cross-linked polyethylene (XLPE) for using in high voltage power cable insulation. This paper aims to determine the effects of different types of nitride-based nanoparticles on the dielectric and mechanical properties of PP. Thus, three nitride-based fillers, boron nitride, aluminium nitride and silicon nitride are selected. To evaluate the influence of different filler concentrations, PP nanocomposite systems containing 5 or 10 wt.% of nitride-based nanoparticles were prepared by a modified solution blending method. Meanwhile, 5 g of neat PP was made with the same procedure to be the reference system. For determining the most suitable fillers in terms of electromechanical properties, three experiments namely, AC breakdown, dielectric spectroscopy and tensile test were conducted. The results of these experiments indicate PP with 5 wt.% of boron nitride has the best performance on dielectric and mechanical properties among nanocomposites.
机译:可回收利用且易于加工的聚丙烯(PP)有望成为用于高压电力电缆绝缘中的常规交联聚乙烯(XLPE)的有前途的替代品。本文旨在确定不同类型的基于氮化物的纳米粒子对PP介电和机械性能的影响。因此,选择了三种氮化物基填料,氮化硼,氮化铝和氮化硅。为了评估不同填料浓度的影响,通过改进的溶液共混方法制备了包含5或10 wt。%氮化物基纳米颗粒的PP纳米复合材料体系。同时,以相同的程序制备5g的纯PP作为参比系统。为了确定就机电性能而言最合适的填料,进行了三个实验,即交流击穿,介电谱和拉伸试验。这些实验的结果表明,具有5重量%的氮化硼的PP在纳米复合材料中具有最佳的介电性能和机械性能。

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