Synthesis And Characterization of Soybean Oil Based Unsaturated Polyester Resin

摘要

A novel soybean oil monoglyceride based unsaturated polyester resin (SOMGUPR) was prepared using two step polymerization with soybean oil,glycerol,1.2-propanediol,maleric anhydride and phthalic anhydride.FT-IR spectroscopy,Gel Permeation Chromatography (GPC) and 1H-NMR spectroscopy were employed to study the chemical structure and molecular weight of this unsaturated polyester resin.The results show that 190°C is the optimal temperature to controll the extent of estification reaction.The number-average molecular weight(Mn) decrease with the increasing value of nglycerol:nsoybean oil in SMOGUPR.Also,the side reaction between SOMG and maleric anhydride has not occured as evidenced by 1H-NMR spectroscopy.