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Oxygen storage capacity in Perovskite-related oxides: The role of over-stoichiometric oxygen in three-way catalysis

机译:钙钛矿相关氧化物的储氧能力:化学计量过剩的氧在三元催化中的作用

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Two perovskite-related catalysts doped with small amounts of noble metals, LaMn_(0.976)Rh_(0024)O_(3+delta) and La_2Cu_(0.9)Pd_(0.1)O_(4+delta), present high activity for three-way catalysis reactions including the simultaneous removal of CO, NO and C_3H_6. These catalysts exhibit oxygen storage properties, evidenced in step-change experiments where CO was oxidised by the lattice oxygen of the solids, at low temperature (400 deg C). These properties allow them to compensate for the fluctuation of the feedstream stoichiometry, when the activity is evaluated under cycling conditions.
机译:两种掺杂有少量贵金属的钙钛矿相关催化剂,LaMn_(0.976)Rh_(0024)O_(3 + delta)和La_2Cu_(0.9)Pd_(0.1)O_(4 + delta)表现出高的三向活性催化反应,包括同时去除CO,NO和C_3H_6。这些催化剂表现出储氧性能,在逐步变化的实验中得到了证明,其中在低温(400摄氏度)下,CO被固体的晶格氧氧化。当在循环条件下评估活性时,这些性质允许它们补偿进料流化学计量的波动。

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