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The anomalous level shift due to local electric modes in confined systems

机译:密闭系统中由于局部电模式导致的异常电平移动

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摘要

The shift of the electron energy level due to the coupling with the surface electromagnetic mode of the cluster is studied. The energy shift is shown to depend on the cluster size and to be much larger than the standard Lamb shift due to the delocalized electromagnetic modes. The angular momentum theory is developed for the calculation of the high-frequency response of the cluster and applied, within the spherical approach, for the computation of the energy shift in the fullerene as an example.
机译:研究了由于与团簇的表面电磁模式耦合而引起的电子能级的移动。由于离域电磁模式,能量位移显示为取决于簇的大小,并且比标准的兰姆位移大得多。角动量理论是为计算簇的高频响应而开发的,并在球形方法中被用于计算富勒烯中的能量位移。

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