首页> 外文会议>International Conference on Separation Science and Technology(ICSST'2007); 20071014-16; Beijing(CN) >Experiment of Molar Excess Enthalpies for Water + 1,2- Ethanediol and some Thermodynamic Properties Calculation
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Experiment of Molar Excess Enthalpies for Water + 1,2- Ethanediol and some Thermodynamic Properties Calculation

机译:水+ 1,2-乙二醇摩尔过量焓的实验及一些热力学性质的计算

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This paper reports experimental molar excess enthalpies HE of the binary system water + 1,2-ethanediol. Measurements have been carried out at 298.15, 313.15, 323.15K temperatures and ambient pressure, using a Calvet Setaram BT2.15 microcalorimeter. The results were fitted by Redlich-Kister equation. From R-K fitting equation, the partial excess enthalpies at different temperatures have been calculated, and the expression of excess heat capacities has been derived.
机译:本文报告了二元体系水+ 1,2-乙二醇的实验摩尔过量焓HE。使用Calvet Setaram BT2.15微量热量计在298.15、313.15、323.15K温度和环境压力下进行了测量。结果由Redlich-Kister方程拟合。根据R-K拟合方程,计算了不同温度下的部分过量焓,并得出了过量热容量的表达式。

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