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Characterization of Piezoresistive Microcantilever Sensors with Metal Organic Frameworks for the Detection of Volatile Organic Compounds

机译:带有金属有机框架的压阻微悬臂梁传感器的特征,用于检测挥发性有机化合物

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摘要

Metal-Organic frameworks (MOFs) with their high surface area, excellent chemical and thermal stability and analyte specific adsorption make them promising material for gas sensing/storage. In this paper, a vapor detection sensor based on HKUST-1 MOF is presented. HKUST-1 with the above mentioned properties makes it an ideal material to be used with strain based piezoresistive microcantilever sensor. Cantilever sensors which were fabricated, characterized and coated with HKUST-1 were exposed to different Volatile Organic Compounds (VOCs) including acetone, isopropanol, methanol and water at varying concentrations. From our experiments, we observe that the device is able to distinguish between the different analytes quantitatively based on their time constants for adsorption or desorption. The results show that acetone has the highest time constant while water has the lowest time constant.
机译:金属有机骨架(MOF)具有高的表面积,出色的化学和热稳定性以及特定于分析物的吸附能力,使其成为有前景的气体传感/存储材料。本文提出了一种基于HKUST-1 MOF的蒸汽检测传感器。具有上述特性的HKUST-1使其成为与基于应变的压阻微悬臂梁传感器一起使用的理想材料。将制造,表征并涂有HKUST-1的悬臂式传感器暴露于不同浓度的挥发性有机化合物(VOC)中,其中包括丙酮,异丙醇,甲醇和水。从我们的实验中,我们观察到该设备能够根据其吸附或解吸的时间常数定量区分不同的分析物。结果表明,丙酮具有最高的时间常数,而水具有最低的时间常数。

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  • 会议地点 Honolulu HI(US)
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    G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, 30332;

    G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, 30332;

    Intel Corporation, Rio Rancho, NM, 87124;

    G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, 30332;

    Sandia National Laboratories, Livermore, CA, 94551;

    Sandia National Laboratories, Livermore, CA, 94551;

    Sandia National Laboratories, Albuquerque, NM, 87185;

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