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Industrial Use of Brazilian Bentonite Modified by Mild Acid Attack

机译:温和酸侵蚀改性的巴西膨润土的工业用途

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摘要

Treatments with high concentration solution of inorganic acid at temperatures under boiling point are a usual method for clay minerals structure modification. For many industrial uses bentonites must be cleared of impurities. In the present paper, a sample of Brazilian bentonite from Vitoria da Conquista, Bahia was modified by mild acid attack using hydrochloric acid under moderate conditions (90 ℃, reaction times of 1, 6, 12, 18 and 24 h in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, acid solution/clay ratio of 1 g/10 mL). The attacked samples were characterized by CEC, XRF, SEM, EDS and Stereomicroscopy. The purpose of these attacks is to reduce the concentration of impurities with minimal damage in clay minerals structure. The modified bentonite presented good results and tends to be a good economic and environmental alternative to manufacturing products with high added value such as polymer/clay nanocomposites, cosmetics and medicines.
机译:在沸点温度下用高浓度的无机酸溶液处理是粘土矿物结构改性的常用方法。对于许多工业用途,必须清除膨润土中的杂质。本文在温和的条件下(90℃,在密闭反应器中反应时间为1、6、12、18和24 h),使用盐酸在温和的酸蚀条件下对来自巴伊亚州维多利亚市的巴西膨润土样品进行了改性。盐酸水溶液1.5M,酸溶液/粘土比为1g / 10mL)。通过CEC,XRF,SEM,EDS和立体显微镜对被侵蚀的样品进行了表征。这些攻击的目的是在粘土矿物结构破坏最小的情况下降低杂质浓度。改性膨润土表现出良好的效果,并且往往是制造高附加值产品(例如聚合物/粘土纳米复合材料,化妆品和药品)的良好经济和环境替代品。

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  • 来源
  • 会议地点 San Diego(US)
  • 作者单位

    Department of Metallurgical and Materials Engineering, EPUSP, Escola Politecnica Universidade Sao Paulo, Sao Paulo, SP 05508-900, Brazil;

    Department of Metallurgical and Materials Engineering, EPUSP, Escola Politecnica Universidade Sao Paulo, Sao Paulo, SP 05508-900, Brazil;

    Department of Metallurgical and Materials Engineering, EPUSP, Escola Politecnica Universidade Sao Paulo, Sao Paulo, SP 05508-900, Brazil;

    Department of Metallurgical and Materials Engineering, EPUSP, Escola Politecnica Universidade Sao Paulo, Sao Paulo, SP 05508-900, Brazil;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Bentonite; Clay; Industrial use; Mild acid attack;

    机译:膨润土粘土;工业用途;轻度酸攻击;

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