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Thermodynamic Properties of Dilute Aluminum in Liquid Zinc

机译:液态锌中稀铝的热力学性质

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The thermodynamic properties of the liquid zinc-aluminum system, in the range of 0 to 0.36 mole fraction of aluminum, were investigated by using an electromotive force (EMF) cell of the type; Al(s) (LiCl-KCl-AlCl_3) Zn-Al (1), Mo he activity of aluminum was found to show a significant positive deviation from Raoultain behavior in the temperature range 430 to 530degC. The activity coefficient of aluminum in dilute solution (gamma~o) and the free energy of dissolution of aluminum based on the one weight percent (1 wt
机译:通过使用该类型的电动势(EMF)电池,研究了液态锌铝体系的热力学性质,铝的摩尔分数为0至0.36。发现Al(s)(LiCl-KCl-AlCl_3)Zn-Al(1),铝的Mo he活性在430至530°C的温度范围内显示出与拉乌兰特行为的显着正偏差。铝在稀溶液中的活度系数(γo)和以1重量百分比(1 wt%

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