AbstractVariation of molecular architectures of blend compatibilizers and reactive processing reaction conditions gave excellent control on morphology development and toughness/stiffness balance of polypropene/polyamide 6 blends. Basic structure/property relationships of blends containing discrete PA6 phases, PA6 nanoparticle cores encapsulated in a rubber shell, dispersed PA6 particles with rubber subinclusions, and percolation structures of agglomerated core/shell particles were investigated. Deformation behavior of percolation structures were analyzed by means of high‐voltage transmission electron microscop
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